From: Advancements in the biopolymer films for food packaging applications: a short review
Application | Composition (polymers) | Component responsible for the application | Application | References |
---|---|---|---|---|
Anti-sprouting films | Carboxymethyl cellulose | coarse emulsions and nanoemulsions of citral | Application suppression of potato tuber sprouting | [4] |
Cross-linked films | Different polymers with organic acids | Synthetic cross-linkers: Divalent calcium salts, sodium tripolyphosphate, N,N′-methylene bisacrylamide, ethylene glycol dimethacrylate, poly (ethylene glycol) diacrylates, epichlorohydrin, and glutaraldehyde. Natural: (Gallic, vanillic, cinnamic, caffeic, ferulic, tannic, citric, succinic, salicylic, rosmarinic acids, etc.) | To improve the physical and chemical properties of the film | |
Active films | Â | Natural additives (glucosides, polysaccharides, phytosterols, phenolic acids, esters, carotenoids, tannins, alkaloids, anthocyanins, flavonoids, terpenoids, caffeic acid, and other organic acids) | To reduce the surface multiplication of pathogenic microorganisms and prevent food deterioration | [37] |
Multilayer films | The hydrophobic zein outer layer, hybrid zein/gelatin middle layer, and the hydrophilic gelatin inner layer | Tea polyphenol | To improve water barrier property | [38] |
pH-sensitive films | Corn starch | Anthocyanins | Real-time quality assessment for packaged food products, as film color of changed from pink to purple and blue, as a function of the pH | [39] |
Buckwheat starch | Natural rose petal extract | |||
Composite films (multicomponent films) | Binary/ ternary/multiple biopolymers from, protein, polysaccharides, and lipids | Different active components have been reported | To improve the physical and chemical properties of primary polymer | [40] |
Super-hydrophobic films | Chitosan | Tea polyphenol-carnauba wax material | extremely low water-absorbing quality | [40] |
Thermal stable films | Polylactic acid | Bionano calcium carbonate | Thermal properties improved after incorporation of nano-CaCO3 | [41] |
polysaccharide/gelatin | - | incorporation of gelatin into soybean polysaccharide films increased the thermal stability | [20] | |
Nano-engineered films | Chitosan | Zinc oxide nanoparticles with pomegranate peel active phenol compounds | For the preservation of pomegranate arils | [42] |
Moisture resistant films | Mung bean starch | Sunflower seed oil | Increase in water-resistance properties | [17] |
High-performance UV-blocking films | Alginate, Whey Protein | Curcumin | Incorporation of Curcumin enhanced UV-blocking efficiency within the films | [43] |
Two-dimensional films | Different polymers | Graphene, transition metal dichalcogenides, hexagonal boron nitride, layered double hydroxides, graphitic carbon nitride, transition metal carbides and nitrides | Improve mechanical, thermal, surface area, and electrocatalytic activity | [7] |
Multi-Shaded films | Gelatin and starch | Food grade colorants | To attract the customers | [8] |
High-barrier water vapor-resistant films | Hydrophobic polymers such as cellulose derivatives (such as ethyl cellulose), Polylactic acid | Food grade essential/vegetable oils, waxes, fats, gums, suitable plasticizers that are compatible with polymers | To improve the barrier property against water vapors | |
Carbon dioxide scavenging films | Different polymers such as zein and cellulose derivate | Carbon dioxide absorbers (Activated carbon, Zeolite, Ca(OH)2, Na2CO3 can be used. Plasticizer can also improve the gas transmission | To improve the barrier property against carbon dioxide | |
Ethylene-absorbing films | Â | Â | to absorb ethylene gas | [49] |
Oxygen scavenging films | Starch, cellulose nanocrystals, polyhydroxyalkanoate, whey protein | Starch-highly ordered hydrogen-bonded network structure (increased crystallinity or higher amylopectin content in the sample improves the barrier properties), likewise, other polymers have inherent properties to control oxygen transmission. In addition, food-grade natural/synthetic antioxidants absorb and remove oxygen from the packaging | These films absorb and remove oxygen from the packaging, which helps to slow down the oxidation process | |
Superior Ductile | Poly(lactic acid) | Biaxial stretching and constrained annealing to induce oriented nano-sized crystals induced | Sustainable packaging | [51] |