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Table 1 Plant-based biopolymers and their applications

From: Biobased polymers of plant and microbial origin and their applications - a review

Biopolymer

Sources

Polymer Composition

Polymer Properties

Applications

Reference

Cellulose

Plant cell wall

Linear polymer of β-1,4-linked D-glucose units

Renewable, biodegradable, biocompatible, good physical and biological characteristics, enhances mechanical strength and stiffness of composites

Tissue engineering scaffolds, wound and burn dressings, medical implants, drug delivery systems, packaging materials

Das et al. 2023 [26]

Starch

Plant seeds (e.g.,corn and wheat) and tubers (e.g., potatoesand cassava)

Composed of amylose and amylopectin polysachharides

Biodegradable, thermoplastic, exhibits good film-forming properties

Drug delivery application and in paper and cardboard manufacturing

Watcharakitti et al. 2022 [129]

Xylan

Cell wall of wood and annual plants

Composed of 1,4-β-D-xylopyranose units with branched carbohydrate chains

Biodegradable, film-forming ability, variable mechanical strength depending on composition and processing conditions

In paper industry, textile printing and as sweetener and preservative in various food products

Nechita et al. 2021 [85]

Chitosan

Mushrooms

Polysaccharide composed of β-(1–4)-linked D-glucosamine units with varying degrees of N-acetylation

Biodegradable, biocompatible, non-toxic, exhibits antimicrobial, and bacteriostatic properties, good film-forming ability

Food packaging material, pharmaceutical applications, waste product valorization

Alimi et al. 2023 [8]

Pectin

Primary cell wall of terrestrial plants

Heteropolysaccharide composed of α-1,4-linked D-galacturonic acid residues with varying degrees of methyl esterification and O-acetylation

Biodegradable, biocompatible, exhibits pH-dependent solubility, forms gels in the presence of calcium ions or at low pH

Wound dressings, tissue engineering scaffolds, and drug delivery systems due to their mucoadhesive properties and injectable hydrogels, antibacterial and anticancer activities

Sultana 2023 [120]

Guar Gum

Guar Seed

Composed mainly of galactomannan, consisting of a backbone of β-D-1,4-linked mannose residues with side chains of α-D-galactose residues

exhibits pseudoplastic (shear-thinning) behaviour, biodegradable

Application is food emulsion, dietary supplement in broiler diets and supplementing it with β-mannanase to which restores the microbiota composition

Saha et al. 2017 [106], Tahmouzi et al. 2023 [123]

Alginate

Extracted from the cell walls of red seaweeds (Rhodophyta)

Linear copolymer composed of alternating blocks of α-(1 → 4)-linked L-guluronic acid and β-(1 → 4)-linked D-mannuronic acid residues

Biodegradable, biocompatible, forms gels in the presence of divalent cations

Used in drug delivery systems, food thickening agents, stabilizer in emulsions, tissue engineering and as a component in biodegradable packaging materials

Szabó et al. 2020 [122]

Carrageenan

Extracted from the cell walls of red seaweeds (Rhodophyta)

Composed of linear polysaccharides, primarily consisting of alternating units of D-galactose and 3,6-anhydrogalactose

Biodegradable, biocompatible, forms gels in the presence of potassium or calcium ions, exhibits excellent thickening and stabilizing properties

Used in food products as a thickening agent, for drug delivery systems, potential in developing hydrogels and composite materials

Pacheco-Quito et al. 2020 [89]

Acacia Gum

Bark of Acacia tree

A complex mixture of polysaccharides (primarily arabinogalactan) and glycoproteins

non-toxic, biodegradable, excellent emulsifying and stabilizing properties

Used as a thickener, stabilizer, tissue engineering, used in enhanced oil recovery

Koyyada and Orsu 2021 [54], Adewunmi et al. 2022 [4], Abou-alfitooh et al. 2024 [2]